3-Cyano-N-methylpyridinium bromide

Joel T. Mague; Ryan M. Ivie; Robert W. Hartsock; Lynn Vogel Koplitz; Mary Spulak

doi:10.1107/S1600536805006264

3-Cyano-N-methylpyridinium bromide

Joel T. Mague, Ryan M. Ivie, Robert W. Hartsock, Lynn Vogel Koplitz, Mary Spulak

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The crystal structure of 3-Cyano-N-methylpyridinium bromide, the isostructural bromide salt, was described. It was found that 3-Cyano-N-methylpyridinium bromide compound has crystallographic mirror symmetry. It was observed that the compound forms a layered solid with each cation forming three strong and one weaker C-H···Br hydrogen bonds within the layer. Consistent with the presence of moderately strong intermolecular interactions, the compound was found to decompose with charring at 493 K.

Original language	English (US)
Pages (from-to)	o851-o853
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	4
DOIs	https://doi.org/10.1107/S1600536805006264
State	Published - Apr 2005
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "3-Cyano-N-methylpyridinium bromide",

abstract = "The crystal structure of 3-Cyano-N-methylpyridinium bromide, the isostructural bromide salt, was described. It was found that 3-Cyano-N-methylpyridinium bromide compound has crystallographic mirror symmetry. It was observed that the compound forms a layered solid with each cation forming three strong and one weaker C-H···Br hydrogen bonds within the layer. Consistent with the presence of moderately strong intermolecular interactions, the compound was found to decompose with charring at 493 K.",

author = "Mague, {Joel T.} and Ivie, {Ryan M.} and Hartsock, {Robert W.} and Koplitz, {Lynn Vogel} and Mary Spulak",

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language = "English (US)",

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T1 - 3-Cyano-N-methylpyridinium bromide

AU - Mague, Joel T.

AU - Ivie, Ryan M.

AU - Hartsock, Robert W.

AU - Koplitz, Lynn Vogel

AU - Spulak, Mary

PY - 2005/4

Y1 - 2005/4

N2 - The crystal structure of 3-Cyano-N-methylpyridinium bromide, the isostructural bromide salt, was described. It was found that 3-Cyano-N-methylpyridinium bromide compound has crystallographic mirror symmetry. It was observed that the compound forms a layered solid with each cation forming three strong and one weaker C-H···Br hydrogen bonds within the layer. Consistent with the presence of moderately strong intermolecular interactions, the compound was found to decompose with charring at 493 K.

AB - The crystal structure of 3-Cyano-N-methylpyridinium bromide, the isostructural bromide salt, was described. It was found that 3-Cyano-N-methylpyridinium bromide compound has crystallographic mirror symmetry. It was observed that the compound forms a layered solid with each cation forming three strong and one weaker C-H···Br hydrogen bonds within the layer. Consistent with the presence of moderately strong intermolecular interactions, the compound was found to decompose with charring at 493 K.

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U2 - 10.1107/S1600536805006264

DO - 10.1107/S1600536805006264

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SP - o851-o853

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

3-Cyano-N-methylpyridinium bromide

Abstract

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