Reversed-phase high-performance liquid chromatography of C5 to C20 isoprenoid benzoates and naphthoates

T. H. Yang; T. M. Zabriskie; C. D. Poulter

doi:10.1016/s0076-6879(85)11013-x

Reversed-phase high-performance liquid chromatography of C₅ to C₂₀ isoprenoid benzoates and naphthoates

T. H. Yang, T. M. Zabriskie, C. D. Poulter

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Benzoate and naphthoate esters of C₅ to C₂₀ isoprenoid alcohols are excellent derivatives for reversed-phase liquid chromatography. Nonlinear responses of log k' to changes in the composition of the mobile phase are observed on Radial PAK C₁₈ columns. In general, the capacity factors (k') increased with increases in carbon content and decreased with increases in the number of double bonds, branching, and Z double bond content. The large extinction coefficients of the aromatic ester moieties, especially the 2-naphthoates, provide high sensitivity for UV detection.

Original language	English (US)
Pages (from-to)	252-263
Number of pages	12
Journal	Methods in Enzymology
Volume	VOL. 111
DOIs	https://doi.org/10.1016/s0076-6879(85)11013-x
State	Published - 1985
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Molecular Biology

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abstract = "Benzoate and naphthoate esters of C5 to C20 isoprenoid alcohols are excellent derivatives for reversed-phase liquid chromatography. Nonlinear responses of log k' to changes in the composition of the mobile phase are observed on Radial PAK C18 columns. In general, the capacity factors (k') increased with increases in carbon content and decreased with increases in the number of double bonds, branching, and Z double bond content. The large extinction coefficients of the aromatic ester moieties, especially the 2-naphthoates, provide high sensitivity for UV detection.",

author = "Yang, {T. H.} and Zabriskie, {T. M.} and Poulter, {C. D.}",

year = "1985",

doi = "10.1016/s0076-6879(85)11013-x",

language = "English (US)",

volume = "VOL. 111",

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journal = "Methods in Enzymology",

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T1 - Reversed-phase high-performance liquid chromatography of C5 to C20 isoprenoid benzoates and naphthoates

AU - Yang, T. H.

AU - Zabriskie, T. M.

AU - Poulter, C. D.

PY - 1985

Y1 - 1985

N2 - Benzoate and naphthoate esters of C5 to C20 isoprenoid alcohols are excellent derivatives for reversed-phase liquid chromatography. Nonlinear responses of log k' to changes in the composition of the mobile phase are observed on Radial PAK C18 columns. In general, the capacity factors (k') increased with increases in carbon content and decreased with increases in the number of double bonds, branching, and Z double bond content. The large extinction coefficients of the aromatic ester moieties, especially the 2-naphthoates, provide high sensitivity for UV detection.

AB - Benzoate and naphthoate esters of C5 to C20 isoprenoid alcohols are excellent derivatives for reversed-phase liquid chromatography. Nonlinear responses of log k' to changes in the composition of the mobile phase are observed on Radial PAK C18 columns. In general, the capacity factors (k') increased with increases in carbon content and decreased with increases in the number of double bonds, branching, and Z double bond content. The large extinction coefficients of the aromatic ester moieties, especially the 2-naphthoates, provide high sensitivity for UV detection.

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VL - VOL. 111

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JO - Methods in Enzymology

JF - Methods in Enzymology

ER -

Reversed-phase high-performance liquid chromatography of C₅ to C₂₀ isoprenoid benzoates and naphthoates

Abstract

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