Role of the Five-Coordinate Intermediate in the Stereochemistry of Dissociative Reactions of Octahedral Compounds

Charles S. Springer

doi:10.1021/ja00786a019

Role of the Five-Coordinate Intermediate in the Stereochemistry of Dissociative Reactions of Octahedral Compounds

Charles S. Springer

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Compound topological graphs have been presented which allow the systematic analysis of the stereochemical aspects of any substitution or stereoisomerization reaction of an octahedral six-coordinate compound which proceeds via a five-coordinate intermediate capable of rearranging according to the Berry pseudorotation mechanism. Examples are given of a substitution reaction of a complex with monodentate ligands and intramolecular isomerization reactions of tris bidentate chelates.

Original language	English (US)
Pages (from-to)	1459-1467
Number of pages	9
Journal	Journal of the American Chemical Society
Volume	95
Issue number	5
DOIs	https://doi.org/10.1021/ja00786a019
State	Published - Mar 1 1973
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja00786a019

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abstract = "Compound topological graphs have been presented which allow the systematic analysis of the stereochemical aspects of any substitution or stereoisomerization reaction of an octahedral six-coordinate compound which proceeds via a five-coordinate intermediate capable of rearranging according to the Berry pseudorotation mechanism. Examples are given of a substitution reaction of a complex with monodentate ligands and intramolecular isomerization reactions of tris bidentate chelates.",

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AB - Compound topological graphs have been presented which allow the systematic analysis of the stereochemical aspects of any substitution or stereoisomerization reaction of an octahedral six-coordinate compound which proceeds via a five-coordinate intermediate capable of rearranging according to the Berry pseudorotation mechanism. Examples are given of a substitution reaction of a complex with monodentate ligands and intramolecular isomerization reactions of tris bidentate chelates.

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Role of the Five-Coordinate Intermediate in the Stereochemistry of Dissociative Reactions of Octahedral Compounds

Abstract

ASJC Scopus subject areas

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