TY - JOUR
T1 - Studies on a model copper mono-oxygenase system
T2 - Peroxo-Cuii binuclear intermediates in the hydroxylation of an aromatic ring
AU - Blackburn, Ninian J.
AU - Karlin, Kenneth D.
AU - Concannon, Martin
AU - Hayes, Jon C.
AU - Gultneh, Yilma
AU - Zubieta, Jon
PY - 1984
Y1 - 1984
N2 - Hydrogen peroxide reacts with a Cuii complex of a m-xylyl binucleating ligand with concomitant hydroxylation to give a phenoxo-bridged complex (previously found as the product of the reaction of dioxygen with the Cui analogue) whereas a newly synthesized mononuclear analogue is unreactive, thereby implicating μ-peroxo-Cuii intermediates in the hydroxylation reaction.
AB - Hydrogen peroxide reacts with a Cuii complex of a m-xylyl binucleating ligand with concomitant hydroxylation to give a phenoxo-bridged complex (previously found as the product of the reaction of dioxygen with the Cui analogue) whereas a newly synthesized mononuclear analogue is unreactive, thereby implicating μ-peroxo-Cuii intermediates in the hydroxylation reaction.
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U2 - 10.1039/C39840000939
DO - 10.1039/C39840000939
M3 - Article
AN - SCOPUS:0006977075
SN - 0022-4936
SP - 939
EP - 940
JO - Journal of the Chemical Society - Series Chemical Communications
JF - Journal of the Chemical Society - Series Chemical Communications
IS - 14
ER -