Synthesis and characterization of a functionalized chiral biaryl capable of exhibiting unidirectional bond rotation

Bart J. Dahl; Bruce P. Branchaud

doi:10.1016/j.tetlet.2004.10.147

Synthesis and characterization of a functionalized chiral biaryl capable of exhibiting unidirectional bond rotation

Bart J. Dahl
, Bruce P. Branchaud

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

A class of chiral biaryl molecules that have been designed to undergo unidirectional rotation about the aryl-aryl bond may show promise for future application in the area of synthetic molecular motors. These asymmetric molecules should be capable of channeling chemical energy into repeated 360° rotation in one direction. Herein we report the synthesis and characterization of one such biaryl molecule (1).

Original language	English (US)
Pages (from-to)	9599-9602
Number of pages	4
Journal	Tetrahedron Letters
Volume	45
Issue number	52
DOIs	https://doi.org/10.1016/j.tetlet.2004.10.147
State	Published - Dec 20 2004
Externally published	Yes

Funding

We are grateful to NSF-CHE-9986926, PRF # 35372AC-1, the US Department of Education GAANN P200A010222-03, and the NSF-IGERT DGE-0114419 for financial support. We thank Jonathan Bingham for some preliminary contributions to this work.

Funders	Funder number
NSF-CHE-9986926	35372AC-1
NSF-IGERT	DGE-0114419
US Department of Education	GAANN P200A010222-03

Keywords

Directed bond rotation
Molecular motors
Nanomachines

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2004.10.147

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title = "Synthesis and characterization of a functionalized chiral biaryl capable of exhibiting unidirectional bond rotation",

abstract = "A class of chiral biaryl molecules that have been designed to undergo unidirectional rotation about the aryl-aryl bond may show promise for future application in the area of synthetic molecular motors. These asymmetric molecules should be capable of channeling chemical energy into repeated 360° rotation in one direction. Herein we report the synthesis and characterization of one such biaryl molecule (1).",

keywords = "Directed bond rotation, Molecular motors, Nanomachines",

author = "Dahl, \{Bart J.\} and Branchaud, \{Bruce P.\}",

note = "Funding Information: We are grateful to NSF-CHE-9986926, PRF \# 35372AC-1, the US Department of Education GAANN P200A010222-03, and the NSF-IGERT DGE-0114419 for financial support. We thank Jonathan Bingham for some preliminary contributions to this work. ",

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doi = "10.1016/j.tetlet.2004.10.147",

language = "English (US)",

volume = "45",

pages = "9599--9602",

journal = "Tetrahedron Letters",

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T1 - Synthesis and characterization of a functionalized chiral biaryl capable of exhibiting unidirectional bond rotation

AU - Dahl, Bart J.

AU - Branchaud, Bruce P.

N1 - Funding Information: We are grateful to NSF-CHE-9986926, PRF # 35372AC-1, the US Department of Education GAANN P200A010222-03, and the NSF-IGERT DGE-0114419 for financial support. We thank Jonathan Bingham for some preliminary contributions to this work.

PY - 2004/12/20

Y1 - 2004/12/20

N2 - A class of chiral biaryl molecules that have been designed to undergo unidirectional rotation about the aryl-aryl bond may show promise for future application in the area of synthetic molecular motors. These asymmetric molecules should be capable of channeling chemical energy into repeated 360° rotation in one direction. Herein we report the synthesis and characterization of one such biaryl molecule (1).

AB - A class of chiral biaryl molecules that have been designed to undergo unidirectional rotation about the aryl-aryl bond may show promise for future application in the area of synthetic molecular motors. These asymmetric molecules should be capable of channeling chemical energy into repeated 360° rotation in one direction. Herein we report the synthesis and characterization of one such biaryl molecule (1).

KW - Directed bond rotation

KW - Molecular motors

KW - Nanomachines

UR - https://www.scopus.com/pages/publications/9644294407

UR - https://www.scopus.com/pages/publications/9644294407#tab=citedBy

U2 - 10.1016/j.tetlet.2004.10.147

DO - 10.1016/j.tetlet.2004.10.147

M3 - Article

AN - SCOPUS:9644294407

SN - 0040-4039

VL - 45

SP - 9599

EP - 9602

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 52

ER -

Synthesis and characterization of a functionalized chiral biaryl capable of exhibiting unidirectional bond rotation

Abstract

Funding

Keywords

ASJC Scopus subject areas

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