The synthesis and evaluation of new α-hydrogen nitroxides for 'living' free radical polymerization

Rebecca Braslau; Greg O'Bryan; Aaron Nilsen; Jeff Henise; Thanchanok Thongpaisanwong; Erin Murphy; Laura Mueller; Jean Ruehl

doi:10.1055/s-2005-869894

The synthesis and evaluation of new α-hydrogen nitroxides for 'living' free radical polymerization

Rebecca Braslau, Greg O'Bryan, Aaron Nilsen, Jeff Henise, Thanchanok Thongpaisanwong, Erin Murphy, Laura Mueller, Jean Ruehl

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Three N-alkoxyamines were synthesized for use in nitroxide-mediated radical polymerization. Upon thermolysis, they generate new acyclic α-hydrogen nitroxides: one adamantyl substituted and two diol-containing nitroxides. The initiators were tested in polymerization reactions in direct comparison with the initiator derived from the nitroxide TIPNO.

Original language	English (US)
Pages (from-to)	1496-1506
Number of pages	11
Journal	Synthesis
Issue number	9
DOIs	https://doi.org/10.1055/s-2005-869894
State	Published - Jun 6 2005
Externally published	Yes

Keywords

Free radicals
Grignard reaction
Nitrone
Nitroxide
Polymers

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1055/s-2005-869894

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title = "The synthesis and evaluation of new α-hydrogen nitroxides for 'living' free radical polymerization",

abstract = "Three N-alkoxyamines were synthesized for use in nitroxide-mediated radical polymerization. Upon thermolysis, they generate new acyclic α-hydrogen nitroxides: one adamantyl substituted and two diol-containing nitroxides. The initiators were tested in polymerization reactions in direct comparison with the initiator derived from the nitroxide TIPNO.",

keywords = "Free radicals, Grignard reaction, Nitrone, Nitroxide, Polymers",

author = "Rebecca Braslau and Greg O'Bryan and Aaron Nilsen and Jeff Henise and Thanchanok Thongpaisanwong and Erin Murphy and Laura Mueller and Jean Ruehl",

year = "2005",

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doi = "10.1055/s-2005-869894",

language = "English (US)",

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AU - Braslau, Rebecca

AU - O'Bryan, Greg

AU - Nilsen, Aaron

AU - Henise, Jeff

AU - Thongpaisanwong, Thanchanok

AU - Murphy, Erin

AU - Mueller, Laura

AU - Ruehl, Jean

PY - 2005/6/6

Y1 - 2005/6/6

N2 - Three N-alkoxyamines were synthesized for use in nitroxide-mediated radical polymerization. Upon thermolysis, they generate new acyclic α-hydrogen nitroxides: one adamantyl substituted and two diol-containing nitroxides. The initiators were tested in polymerization reactions in direct comparison with the initiator derived from the nitroxide TIPNO.

AB - Three N-alkoxyamines were synthesized for use in nitroxide-mediated radical polymerization. Upon thermolysis, they generate new acyclic α-hydrogen nitroxides: one adamantyl substituted and two diol-containing nitroxides. The initiators were tested in polymerization reactions in direct comparison with the initiator derived from the nitroxide TIPNO.

KW - Free radicals

KW - Grignard reaction

KW - Nitrone

KW - Nitroxide

KW - Polymers

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UR - http://www.scopus.com/inward/citedby.url?scp=20644448605&partnerID=8YFLogxK

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EP - 1506

JO - Synthesis

JF - Synthesis

IS - 9

ER -

The synthesis and evaluation of new α-hydrogen nitroxides for 'living' free radical polymerization

Abstract

Keywords

ASJC Scopus subject areas

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