Abstract
Three N-alkoxyamines were synthesized for use in nitroxide-mediated radical polymerization. Upon thermolysis, they generate new acyclic α-hydrogen nitroxides: one adamantyl substituted and two diol-containing nitroxides. The initiators were tested in polymerization reactions in direct comparison with the initiator derived from the nitroxide TIPNO.
Original language | English (US) |
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Pages (from-to) | 1496-1506 |
Number of pages | 11 |
Journal | Synthesis |
Issue number | 9 |
DOIs | |
State | Published - Jun 6 2005 |
Externally published | Yes |
Keywords
- Free radicals
- Grignard reaction
- Nitrone
- Nitroxide
- Polymers
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry