Aminolysis of epoxides in ionic liquid 1-ethylpyridinium trifluoroacetate as green and efficient reaction medium

Sanjay V. Malhotra; Richard P. Andal; Vineet Kumar

doi:10.1080/00397910802323056

Aminolysis of epoxides in ionic liquid 1-ethylpyridinium trifluoroacetate as green and efficient reaction medium

Sanjay V. Malhotra, Richard P. Andal, Vineet Kumar

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Aminolysis of epoxides has been carried out using the ionic liquid 1-ethylpyridinium trifluoroacetate ([EtPy][TFA]) as reaction medium. The reactions went smoothly under mild conditions without any catalyst to afford corresponding β-aminoalcohols in high conversions. Moreover, further enhancement in the conversions was observed when AlCl3 was used as Lewis acid catalyst.

Original language	English (US)
Pages (from-to)	4160-4169
Number of pages	10
Journal	Synthetic Communications
Volume	38
Issue number	23
DOIs	https://doi.org/10.1080/00397910802323056
State	Published - Jan 2008
Externally published	Yes

Keywords

Aminolysis
Epoxides
Ionic liquids
β-Amino alcohols

ASJC Scopus subject areas

Organic Chemistry

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10.1080/00397910802323056

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abstract = "Aminolysis of epoxides has been carried out using the ionic liquid 1-ethylpyridinium trifluoroacetate ([EtPy][TFA]) as reaction medium. The reactions went smoothly under mild conditions without any catalyst to afford corresponding β-aminoalcohols in high conversions. Moreover, further enhancement in the conversions was observed when AlCl3 was used as Lewis acid catalyst.",

keywords = "Aminolysis, Epoxides, Ionic liquids, β-Amino alcohols",

author = "Malhotra, {Sanjay V.} and Andal, {Richard P.} and Vineet Kumar",

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T1 - Aminolysis of epoxides in ionic liquid 1-ethylpyridinium trifluoroacetate as green and efficient reaction medium

AU - Malhotra, Sanjay V.

AU - Andal, Richard P.

AU - Kumar, Vineet

PY - 2008/1

Y1 - 2008/1

N2 - Aminolysis of epoxides has been carried out using the ionic liquid 1-ethylpyridinium trifluoroacetate ([EtPy][TFA]) as reaction medium. The reactions went smoothly under mild conditions without any catalyst to afford corresponding β-aminoalcohols in high conversions. Moreover, further enhancement in the conversions was observed when AlCl3 was used as Lewis acid catalyst.

AB - Aminolysis of epoxides has been carried out using the ionic liquid 1-ethylpyridinium trifluoroacetate ([EtPy][TFA]) as reaction medium. The reactions went smoothly under mild conditions without any catalyst to afford corresponding β-aminoalcohols in high conversions. Moreover, further enhancement in the conversions was observed when AlCl3 was used as Lewis acid catalyst.

KW - Aminolysis

KW - Epoxides

KW - Ionic liquids

KW - β-Amino alcohols

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U2 - 10.1080/00397910802323056

DO - 10.1080/00397910802323056

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JF - Synthetic Communications

IS - 23

ER -

Aminolysis of epoxides in ionic liquid 1-ethylpyridinium trifluoroacetate as green and efficient reaction medium

Abstract

Keywords

ASJC Scopus subject areas

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