Abstract
It is demonstrated theoretically and experimentally that double-quantum coherence can be excited with nearly maximal efficiency over a large range of spin coupling strengths in NMR with the use of composite excitation sequences. Such sequences are shown to be directly constructible from existing composite π 2 pulses. In addition, a general procedure is given for converting a composite excitation sequence to an equivalent, reduced form that contains fewer rf pulses and simpler rf phase shifts. Experiments are performed on the proton pair of CH2Cl2 oriented in a liquid crystal solvent. Applications to quadrupolar spin-1 nuclei and other dynamically simple multilevel systems are discussed.
Original language | English (US) |
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Pages (from-to) | 54-64 |
Number of pages | 11 |
Journal | Journal of Magnetic Resonance (1969) |
Volume | 62 |
Issue number | 1 |
DOIs | |
State | Published - Mar 1985 |
Externally published | Yes |