Abstract
Objectives: To test the influence of photoinitiator type and filler particle inclusion on the validity of exposure reciprocity law. Materials and methods: 50/50 wt% Bis-GMA/TEGDMA resins were prepared with equimolar concentrations of camphorquinone/DMAEMA (0.20/0.80 mass%) (CQ) or Lucirin-TPO (0.42 mass%), and were used either unfilled or filled to 75 mass%. Specimens were cured with a halogen Swiss Master Light (EMS, Switzerland) using four different curing protocols: 400 mW/cm2 for 45 s as reference protocol (18 J/cm2), 1500 mW/cm2 for 12 s (18 J/cm2), 3000 mW/cm2 for 6 s (18 J/cm2) and 3 s (9 J/cm 2). Degree of conversion (DC) was measured in real time for 70 s by FT-NIRS and temperature rise using a thermocouple. Depth of cure was determined with a penetrometer technique. Results: With respect to DC and depth of cure, exposure reciprocity law did not hold for any tested material, except for the depth of cure of filled CQ-based materials. At similar radiant exposure, DC was significantly higher (p < 0.05) for all unfilled and filled TPO-based materials compared with CQ-based materials. As exposure time was reduced and irradiance increased, TPO-based materials exhibited higher DC whilst an opposite trend was observed for CQ-based materials (p < 0.05). For similar curing regimes, depth of cure of CQ-based materials remained significantly greater than that of TPO-based materials. Adding fillers generally reduced DC, except at higher irradiance for CQ-based materials where a positive effect was observed (p < 0.05). Significance: The validity of exposure reciprocity law was dependent on several factors, among which photoinitiator type and filler content were important. Lucirin-TPO is a highly reactive and efficient photoinitiator, which may allow the potential for a reduction in curing time of TPO-based photoactive materials in thin sections.
Original language | English (US) |
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Pages (from-to) | 157-164 |
Number of pages | 8 |
Journal | Dental Materials |
Volume | 27 |
Issue number | 2 |
DOIs | |
State | Published - Feb 2011 |
Keywords
- Degree of conversion
- Dental resin composite
- Depth of cure
- Exposure reciprocity law
- Photoinitiator
- Polymerization kinetics
ASJC Scopus subject areas
- General Materials Science
- General Dentistry
- Mechanics of Materials